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Electroactive Polymers 1: Piezoelectric Materials

Piezoelectric Materials require an input of voltage to change shape. In the 1880s, piezoelectricity was discovered through experiments with quartz done by Jacques and Pierre Curie.

How it works:
         Piezoelectric materials have two crystalline configurations. One structure is organized, while the other is not. Organization of the structure has to do with polarization of the molecules that make up the material. Hence, a non-polarized material has a non-organized structure, while the polarized material is organized. To polarize the material, voltage or electricity must be conducted through it. As a result of this electrical force, the molecules of the material reorient themselves, thus changing the shape of the material; this is called electrostriction.

The picture below shows this process at a microscopic level. Change in shape can produce mechanical force, as well as changes in physical characteristics (like density, shown below).

Non-polarized material:   Polarized material:
Drawing of Non-polarized material:.

On the right, shape change is produced with input of electricity.

On the left, electricity is produced with input of shape change.

Drawing of Polarized material:.

Similarly, if mechanical force is exerted on the material to change its shape, an electrical field is produced; this is called piezoelectric effect. Electrostriction and piezoelectric effect are opposite phenomena. In the graphic below, a thin piezoelectric material within a plastic sheath is being bent, and electricity is being generated and passed through the red wires at the end.

Piezoelectric material within a plastic sheath is 
being bent, electricity

                 is being generated and passed through wires.

PZT is the most popular piezoelectic material in use. Its physical properties can be optimized for certain applications by controlling the chemistry and processing of this material. Therefore, it can have a variety of compositions, geometries, and applications. Limitations in its use are related to high excitation voltages needed, mechanical durability, and stability in coupling the material to the control system and/or structure.

Some piezoelectric materials are:

Examples of Applications and Links:
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Graphic of a conventional wing surface 
and a smart wing surface. Photograph of a smart wing surface.

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